• DocumentCode
    597260
  • Title

    The structure and ionic conductivity of Li0.5−yNayLa0.5 {Nb,Ta}2O6 system

  • Author

    Kobylianska, S.D. ; V´yunov, O.I. ; Gavrilenko, O.N. ; Belous, A.G.

  • Author_Institution
    Vernadskii Institute of General & Inorganic Chemistry, Kyiv, Ukraine
  • fYear
    2012
  • fDate
    3-7 Sept. 2012
  • Firstpage
    285
  • Lastpage
    286
  • Abstract
    We have synthesized Li0.5−yNayLa0.5 Nb2O6 and Li0.5−yNayLa0.5 Ta2O6 defect perovskite solid solutions with 0 < y ≤ 0.5. Lithium ion diffusion in the investigated system exhibits no percolation effect. In the Li0.5−yNayLa0.5 Nb2O6 system, the ionic conductivity as a function of sodium content has a maximum due to two competing factors: the increase in perovskite cell volume and the decrease in lithium ion concentration. The ionic conductivity of Li0.5−yNayLa0.5 Ta2O6 samples decreases with sodium content.
  • Keywords
    Conductivity; Ions; Lithium; Nuclear magnetic resonance; Solids; Temperature measurement; X-ray scattering; NMR; ionic conductivity; niobates; solid-state reactions; tantalates;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Oxide Materials for Electronic Engineering (OMEE), 2012 IEEE International Conference on
  • Conference_Location
    Lviv, Ukraine
  • Print_ISBN
    978-1-4673-4491-3
  • Type

    conf

  • DOI
    10.1109/OMEE.2012.6464765
  • Filename
    6464765
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=597260