Au and Pt Nanoparticles Effects on the Optical and Electrical Gas Sensing Properties of Sol–Gel-Based ZnO Thin-Film Sensors

The optical and conductometric responses of sol-gel-based ZnO thin films with embedded 5% mol. Au or Pt nanoparticles (NPs) have been compared at different operating temperatures, to assess the effect of noble metal additions on to H₂, CO and NO₂ gases sensors response. The scanning electron microscopy and X-ray diffraction techniques have been utilized for morphological characterization of the crystal structures of the films after annealing at 400°C for 30 min and the effect of Au and Pt NPs additions on crystallite growth is discussed. Au NPs additions is effective to enhance the optical response to H₂ and CO at 390 nm and in the 500-700-nm wavelength range at 300- °C temperature. No optical response to NO₂ gas, even at low concentrations has been measured in the optical mode. The catalytic action of Pt NPs additions powerfully improves both the optical to H₂ and CO at 390 nm, and the conductometric gas responses. Detection limits as low as 20-ppb NO₂ and 50-ppm H₂, in line with the best performances reported to the best of our knowledge in literature for ZnO-based sensors, have been measured in the conduction mode. Response times have been also compared, highlighting the positive effects played by Pt additions.