• DocumentCode
    74148
  • Title

    Enhanced Performance in Cu(In,Ga)Se _{\\bf 2} Solar Cells Fabricated by the Two-Step Selenization Process With a Potassium Fluoride Postdeposition Treatment

  • Author

    Mansfield, Lorelle M. ; Noufi, Rommel ; Muzzillo, Christopher P. ; DeHart, Clay ; Bowers, Karen ; To, Bobby ; Pankow, Joel W. ; Reedy, Robert C. ; Ramanathan, Kannan

  • Author_Institution
    Nat. Renewable Energy Lab., Golden, CO, USA
  • Volume
    4
  • Issue
    6
  • fYear
    2014
  • fDate
    Nov. 2014
  • Firstpage
    1650
  • Lastpage
    1654
  • Abstract
    Cu(In,Ga)Se2 (CIGS) solar cells fabricated with twostep selenization processes commonly suffer from low open-circuit voltage (Voc). We found that the Voc of solar cells made from selenized Cu/Ga/In stacked metal precursors can be increased by employing a potassium fluoride (KF) postdeposition treatment (PDT). This study presents a comparison of films and resulting devices with and without the KF PDT. By including the KF PDT, an 18.6%-efficient CIGS device with a Voc of 0.709 V was fabricated using a two-step selenization process.
  • Keywords
    copper compounds; gallium compounds; indium compounds; semiconductor growth; semiconductor thin films; solar cells; ternary semiconductors; vacuum deposition; CIGS solar cells; Cu(InGa)Se2; low open-circuit voltage; metal precursors; potassium fluoride postdeposition treatment; two-step selenization processes; Copper compounds; Performance evaluation; Photovoltaic cells; Photovoltaic systems; Surface treatment; Thin film devices; Copper compounds; Cu(In, Ga)Se2; current–voltage characteristics; current??voltage characteristics; photovoltaic cells; potassium fluoride postdeposition treatment; thin films;
  • fLanguage
    English
  • Journal_Title
    Photovoltaics, IEEE Journal of
  • Publisher
    ieee
  • ISSN
    2156-3381
  • Type

    jour

  • DOI
    10.1109/JPHOTOV.2014.2354259
  • Filename
    6901217