Title :
CVD synthesis and CEMS study of Fe sulphide and oxide thin films
Author :
Rogalski, Mircea S. ; Besserguenev, Valentin ; Barata, Nuno R A ; Baltazar, Raul
Author_Institution :
Phys. Dept., Univ. of Algarve, Faro, Portugal
Abstract :
Ferrous sulphide FeS1+x thin films were obtained by chemical vapor deposition (CVD), using Fe[(C2H5)2NCS2]3 as a precursor, and their ferrimagnetic structure was characterized by conversion electron Mossbauer spectroscopy (CEMS) in relation with the deposition temperature. Magnetite and hematite thin films were prepared, with stoichiometry determined from their CEMS spectra, by thermal treatment under variable air pressure of the CVD as-cast films.
Keywords :
CVD coatings; Mossbauer effect; ferrimagnetic materials; iron compounds; magnetic thin films; stoichiometry; CEMS; CVD synthesis; Fe sulphide film; Fe2O3; FeS1+x; FeS1+x thin films; Fe[(C2H5)2NCS2]3; chemical vapor deposition; conversion electron Mossbauer spectroscopy; deposition temperature; ferrimagnetic structure; hematite thin films; magnetite thin films; Chemical analysis; Chemical vapor deposition; Electrons; Ferrimagnetic films; Iron; Magnetic films; Sputtering; Substrates; Temperature; Transistors;
Journal_Title :
Magnetics, IEEE Transactions on
DOI :
10.1109/TMAG.2003.815565