Monitoring the Synthesis and Composition Analysis of Microsilica Encapsulated Acetylacetonatocarbonyl TriphenylphosphinerhodiumCatalyst by Inductively Coupled Plasma (ICP) Techniques

Author

Dai, Qing ; Menzies, David ; Wang, Qiang ; Ostafin, Agnes E. ; Brown, Seth N. ; Meisel, Dan ; Maginn, Edward J.

Author_Institution

Sch. of Chem. & Sch. of Mater. Eng., Monash Univ., Melbourne, Vic.

Volume

5

Issue

6

fYear

2006

Firstpage

677

Lastpage

682

Abstract

A novel technique to monitor the synthesis process of encapsulated acetylacetonatocarbonyl triphenylphosphinerhodium within a microsilica nanoshell has been studied using inductively coupled plasma (ICP) techniques. Nanospheres sized around 50-100 nm were obtained and ICP was used to quantify the exact composition of rhodium, phosphorous, and silicon with differing digestion solvents. In addition, ICP was used to detect rhodium and phosphorous in the nano core-shell catalysts as a quality control procedure

Keywords

catalysts; nanostructured materials; nanotechnology; organic compounds; plasma materials processing; inductively coupled plasma techniques; microsilica encapsulated acetylacetonatocarbonyl triphenylphosphinerhodium catalyst; microsilica nanoshell; nanocore-shell catalysts; nanotechnology; phosphorous; rhodium; silicon; Australia; Chemistry; Composite materials; Current measurement; Instruments; Monitoring; Plasma applications; Plasma sources; Silicon compounds; Spectroscopy; Encapsulation; Rh catalyst; inductively coupled plasma (ICP); nanotechnology; silica nanoshell;

fLanguage

English

Journal_Title

Nanotechnology, IEEE Transactions on

Publisher

ieee

ISSN

1536-125X

Type

jour

DOI

10.1109/TNANO.2006.876936

Filename

4011924