DocumentCode :
848344
Title :
Structure and magnetic properties of Sm(CobalFexTi0.05)9.66 alloys (x=0-0.57) and Sm(Co0.66Fe0.19Ti0.05Cu0.1)9.66 magnets
Author :
Huang, M.Q. ; Fingers, R.T. ; Turqut, Z. ; Swaminathan, R. ; Johnson, F. ; McHenry, M.E. ; Ma, B.M. ; Ramanan, V.R.
Author_Institution :
UES Inc., Dayton, OH, USA
Volume :
38
Issue :
5
fYear :
2002
fDate :
9/1/2002 12:00:00 AM
Firstpage :
2946
Lastpage :
2948
Abstract :
Potential permanent magnetic materials with compositions of Sm(CobalFexTi0.05)9.66 (x=0-0.57) have been synthesized and characterized in the temperature range of 10-1473 K and at fields up to 5 T. The experimental results show that near single phase materials with Th2Ni17 structure were formed in Sm(CobalFexTi0.05)9.66 alloys after splat quenching from 1473 K. The Ti atoms play an important role in stabilizing the Th2Ni17 structure for the 3d (transition metal) rich nonstoichiometric 2-17 compounds. Encouraging hard magnetic properties with Tc∼890-1066 K, Ms∼10.8-13.7 kG, Ha∼30-125 kOe at 300 K were observed in Sm(CobalFexTi0.05)9.66 alloys. Both Sm(Co0.66Fe0.19Ti0.05Cu0.1)9.66 sintered and melt-spun powder magnets with 4πMs≥10 kG were fabricated. A strong domain wall pinning behavior with Hc∼1.6 kOe at RT and Hc∼4.3 kOe at 10 K was observed. The effect of different heat treatment conditions on the phase formation of Sm(CobalFexTi0.05)9.66 alloys was also discussed.
Keywords :
Curie temperature; cobalt alloys; coercive force; copper alloys; crystal structure; ferromagnetic materials; heat treatment; iron alloys; magnetic anisotropy; magnetic domain walls; magnetisation; melt spinning; permanent magnets; samarium alloys; sintering; splat cooling; titanium alloys; 10 to 1473 K; 5 T; Curie temperature; Sm(Co0.66Fe0.19Ti0.05Cu0.1)9.66; Sm(Co0.66Fe0.19Ti0.05Cu0.1)9.66 magnet; Sm(CobalFexTi0.05)9.66 alloy; Sm(CoFeTi0.05)9.66; Th2Ni17 structure; coercivity; domain wall pinning; hard magnetic properties; heat treatment; high temperature permanent magnet; melt spinning; phase formation; powder magnet; saturation magnetization; single phase material; sintering; splat quenching; structural properties; uniaxial anisotropy; Composite materials; Inorganic materials; Iron alloys; Magnetic materials; Magnetic properties; Magnets; Nickel alloys; Powders; Temperature distribution; Titanium alloys;
fLanguage :
English
Journal_Title :
Magnetics, IEEE Transactions on
Publisher :
ieee
ISSN :
0018-9464
Type :
jour
DOI :
10.1109/TMAG.2002.803179
Filename :
1042419
Link To Document :
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