Title :
Plasma synthesis of ammonia with a microgap dielectric barrier discharge at ambient pressure
Author :
Bai, Mindong ; Zhang, Zhitao ; Bai, Xiyao ; Bai, Mindi ; Ning, Wang
Author_Institution :
Environ. Eng. Res. Inst., Dalian Maritime Univ., Liaoning, China
Abstract :
The plasma synthesis of ammonia has been studied in nitrogen-hydrogen plasma using a microgap dielectric barrier discharge at ambient pressure. With the new technology of dielectric layers, the high-energy electrons are obtained in a narrow discharge gap; meanwhile, N2 and H2 molecules are ionized and dissociated and a large number of free atoms, ions, and radicals are formed in a nonequilibrium plasma after inelastic collisions. The final product was mainly ammonia, and the yield of ammonia reaches 12500 ppm (1.25%). In this way, plasma synthesis of ammonia at ambient pressure is realized and a new method is provided for inorganic synthesis.
Keywords :
ammonia; discharges (electric); ionisation potential; plasma chemistry; plasma materials processing; H2; N2; N2-H2; NH3; ambient pressure; ammonia concentration; ammonia synthesis; ammonia yield; dielectric barrier discharge; high-energy electrons; narrow discharge gap; nitrogen-hydrogen plasma; nonequilibrium plasma process; plasma synthesis; Atomic measurements; Chemicals; Dielectrics; Electrons; Ionization; Iron; Plasma chemistry; Plasma temperature; Radio frequency; Surface discharges;
Journal_Title :
Plasma Science, IEEE Transactions on
DOI :
10.1109/TPS.2003.818761