Title :
The Critical Current Density of Polycrystalline
Prepared by Using Boron Mixture
Author :
Chen, Soo K. ; MacManus-Driscoll, Judith L.
Author_Institution :
Phys. Dept., Univ. Putra Malaysia, Serdang, Malaysia
fDate :
6/1/2009 12:00:00 AM
Abstract :
In this study, boron powders with varying purity and form were mixed in different proportion to serve as precursors for reaction with Mg forming polycrystalline MgB2 bulks. The inductively measured superconducting transition temperature, T c and the critical current density, J c were compared to that of samples prepared from the respective single boron. Overall, T c remains largely unchanged for all samples. It was found that J c at 6 K and 20 K did not degrade significantly up to 4.6 T as a result of adding impure boron as much as 10 wt.% indicating comparable J c can be obtained without dependence of use of expensive high purity boron powder alone. The systematic decrease of J c with increasing impure boron additions shows that a compromise between desired J c and cost reduction can be made by varying the boron powder proportion. Finally, samples prepared from the mixture of both impure crystalline and amorphous borons even show enhanced J c up to 3 T at 20 K. The increase in J c correlates with the retention of strain level in these samples probably resulted from the more similar reaction rate of the respective borons.
Keywords :
critical current density (superconductivity); magnesium compounds; materials preparation; powders; superconducting materials; superconducting transition temperature; MgB2; amorphous boron; boron powders; critical current density; high purity boron powder; polycrystalline sample preparation; pure crystalline boron; superconducting transition temperature; temperature 20 K; temperature 6 K; ${rm MgB}_{2}$; Boron precursors; critical current density; strain;
Journal_Title :
Applied Superconductivity, IEEE Transactions on
DOI :
10.1109/TASC.2009.2018461